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I'm on a Droid running Froyo so I'm not sure if it's going to be exactly the same for you but try Settings->Acconuts & sync. Each account should have options for you to toggle.i've tried that
i dont see data sync under settings?
Can I ask what your actual goal is with this? You'd probably need an app to schedule sync.Also, is there a way to set up a schedule rather then having it connected all the time?