Do you mean in the stock browser you're stuck in the desktop view? If so, go into the Menu, and down the list you'll find a checkbox for "View desktop site". Uncheck it.
That button (double revolving arrow) is to turn on Auto Sync. That's essentially a shortcut for Settings > Accounts & Sync > Auto-Sync ON/OFF. When it's on, it'll sync all accounts based on their respective sync settings. Keep it off if you want to limit your 3G usage.
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