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When Google came out with Nexus 7, you could preorder it at the time. I'm not sure if you could preorder from a retail store though, but I think some stores were taking orders.
I dunno. With all the gigs offered through Google Drive as well as using an OTB USB cable to access an external drive of some sort, space really isn't an issue. 32GB is nice, but if it's just the same 'ol N7 with more disk space, then I'm just content with what I have. Besides, it's always nice to have your stuff backed up on some virtual storage space or external source. Besides, if you're going to save that much stuff and/or work into your tablet where you need at least 32 gigs (realistically, about 28gigs usable), there's no excuse not to back up what you saved.
The online retailers I've seen selling it have it listed cheaper than the 16gb.