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Actually it couldn't be easier. Much easier than setting-up my blackberry when I did that.As I said, I did it that way through Kies for my S2.
It was simple, by checking the approriate boxes.
I do not yet have the S3.
bill94920
S PLanner is the icon for the calandar on the SIII. Look for an icon with a calendar on it. Press Left button/Settings/CalendarsCheck My calendar. Then I use Kies to sync Outlook calendar. You are also able to select Contacts if so required. The options for that are displayed on the Kies Page.

I had the sane problems and resorted to using the apparently MobiMail

I have modified my posting as:-
S PLanner is the icon for the calandar on the SIII. Look for an icon with a calendar on it. Press Left button/Settings/Calendars/ and then Check My calendar. Then I use Kies to sync Outlook calendar. You are also able to select Contacts if so required. The options for that are displayed on the Kies Page. Do you have an icon for S Planner?