Assuming you have the motorola drivers installed there should be a corrosponding icon on the taskbar when the phone is connected. Right click on the icon and you can disable the web page that's launched when the phone is connected.
Right click on the motorola icon on your computer in the bottom right next to the clock. One of the choices will be something to the effect of plug in action or something like that (I'm not at home to tel you exactly what it says). Go to that and select "do nothing"
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