You can make groups and set up each person to be in a group. Then when you go in your contacts, scroll over to the second icon on the left (the groups icon). I can't think of any other way to do it. Hope this is what you're looking for.
if you really need two, one for work and one for family/friends you could always create a separate google account for your work stuff. not sure if you would be able to set which ones show up in people but it may be worth a shot.
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