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Yeah do a nandroid backup, backup sd card to PC then follow the steps to partition.
Assume you used Gparted? if you used rom manager you may struggle as some roms wont boot without the partition...
I dont trust those 32's. I got a 16GB class 10, but now knowing over class 6 is pointless, I'd go for a class 6 16GB
yeah ive got my live cd, im thinking about getting a 32gb but not sure as the ones i can afford are from Hong Kong and most are class 2, but ive found some 16gb class 6 for about