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I did some digging in the Orange support pages and found THIS
It looks like you can have upto 3 POP email accounts pushed to your phone, if you have the "Email on my phone" service. Looks like you start by sending a text to Orange and they reply with a link to Orange World where you enter your POP account details.
Here's what the support section says...
"What is the 'email on your phone' service?
This service allows you to send and receive email messages on your handset from up to three of your personal email addresses
After getting a random SMS from 247 telling me 'not to forget that I can use WAP PUSH email' I hit the same problem. Subscribe, Continue, then nothing.....